I'll be honest, I have 3 crystal balls (one the size of a tennis ball and is Quartz, an Amethyst the size of a softball, and a Green Banded Onyx the size of a grapefruit), and when making each of their pillows I filled an amount of herbs proportional to their size, and the types of herbs I used I went with what I felt matched the balls themselves.
For the Amethyst I used: Apple Seeds, Star Anise, Lavender, and a pinch of Cumin (a binding herb that protects the tools it is with from theft, loss, or what I call "bad juju")
For the Quartz I used: Bay, Orange Peels (dried, of course), Sweet Woodruff, and Cloves (same purpose as the Cumin)
For the Onyx I used: Sweet Basil, Orange and Lemon Thyme, Cinnamon, and Cloves
I also used just a little of Rosemary in each of the pillows because I love it, and because I grow a bunch, and because it feels like a binding herb to me... Something to get all of the other herbs unified and kind of seal my intent. I guess I think of Rosemary is my "signature herb." LOL I also added a few large sea salt "crystals" just for purification.
But according to my book, you can use Acacia, Angelica, Anise, Betony, Borage, Cinquefoil, Clover, Cornflower, Damiana, Datura Seeds, Dittany of Crete, Eyebright, Honeysuckle, Hops, Kelp, Marigold, Mistletoe, Moonwort, Mugwort, Myrrh, Orris Root, Rose Hips, Rosemary, Rowan, Vervain, Willow, Wormwood, Yarrow...
Also, rice and beans and to a lesser extent, dried peas, also have strong divinatory significance.